The reality star, 22, is paired with professional skater Joe Johnson on the hit ITV competition and will perform next week.
During Sunday’s launch show, host Holly, 40, spoke to the six celebrities who will take to the ice floor on Sunday 23 January where Liberty sweetly complimented Holly’s outfit.
Talking to Liberty, Holly said: “So, this is very different from Love Island, I mean it’s a lot colder out there for a start! Are you ready for next week?”
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To which Liberty replied: “It is, definitely. First of all, you look stunning, I love your dress! I am nervous but I’m looking forward to it.
“Me and Joe just have so much fun together training and I just can’t wait!”
Viewers were quick to take to Twitter over the moment as they commented on Liberty’s “sweet” gesture.
One person said: “Liberty telling Holly she looks stunning she’s so sweet #DancingOnIce.”
A different account put: “Liberty is just the sweetest. #DancingOnIce,” followed with heart emojis.
While another show watcher added: “Aww Liberty man [heart eye emojis] #DancingOnIce.”
The TV presenter, 39, is paired with pro Lukasz Rozycki and the duo will perform again next Sunday in a bid to save themselves from being eliminated from the competition.
Ria and Lukasz performed a routine to Treat People With Kindness by Harry Styles, where they received a total of 24.5 points, on Sunday 16 January opening show.
Dancing On Ice hosts Holly and Phillip Schofield delivered the disappointing news as they announced: “Ria and Lukasz you are in the skate-off, please come and join us over here.”
Phillip continued: “Somebody has to be but it’s such a shame that it’s you!” with Holly adding: “I’m so sorry!”
Ria admitted she was “gutted” over the news, she said: “I’m really gutted because we absolutely worked so hard on this skate and I enjoyed every second skating with Lukasz.”
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Dancing On Ice continues on Sundays on ITV at 6:30pm.